
Shandong Do Sender Chemicals Co.,Ltd.
- Organic Peroxide
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- Organic Peroxide
- Hydroperoxides
- Ketone Peroxides
- Alkyl Peroxides
- Acyl Peroxides
- Ester Peroxides
Shandong Do Sender Chemicals Co.,Ltd.
- Organic Peroxide
- Hydroperoxides
- Ketone Peroxides
- Alkyl Peroxides
- Acyl Peroxides
- Ester Peroxides
- …
- Organic Peroxide
- Hydroperoxides
- Ketone Peroxides
- Alkyl Peroxides
- Acyl Peroxides
- Ester Peroxides

Perodox® 101 - 2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane
CAS: 78-63-7
High-temperature initiator for polymerization of styrene, ethylene, and crosslinking of polyethylene with 10.96% active oxygen content
Product Overview
Perodox® 101 is a high-temperature initiator for polymerization of styrene, ethylene, and crosslinking of polyethylene
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane is a high-temperature initiator for the polymerization of styrene, ethylene, and crosslinking of polyethylene. It is also used for the crosslinking of EPDM, EPM, silicone rubber, and the curing of unsaturated polyester resins. Perodox® 101 has a 10-hour half-life temperature of 118°C, making it suitable for high-temperature applications requiring efficient free radical generation.
CAS Number:78-63-7
TSCA Status:Listed on inventory
EINECS/ELINCS No.:201-127-0
Molecular Weight:290.4 g/mol
Active Oxygen Content:10.96%
Purity:90% min.
Appearance:Clear, colorless to pale yellow liquid
Applications
Perodox® 101 is widely used in various high-temperature polymerization and crosslinking applications
Styrene Polymerization
High-temperature initiator for bulk and suspension polymerization of styrene
Ethylene Polymerization
Initiator for high-pressure polymerization of ethylene to produce polyethylene
Polyethylene Crosslinking
Crosslinking agent for polyethylene to improve thermal and mechanical properties
Rubber Crosslinking
Crosslinking agent for EPDM, EPM, and silicone rubber vulcanization
Technical Data
Comprehensive technical specifications and performance characteristics of Perodox® 101
Thermal Stability (SADT)
60°C - Self-Accelerating Decomposition Temperature
Active Oxygen Content
10.96% - Minimum purity 90%
Molecular Weight
290.4 g/mol - High-temperature initiator structure
Packaging
20 kg polyethylene with hazardous material labeling and handling instructions
Safety & Storage
Proper handling and storage procedures for Perodox® 101
Storage Conditions
Maximum Temperature: 25°C (77°F)
Safe Storage: 30°C (86°F) max without loss of activity
When stored under recommended storage conditions, Perodox 101 maintains specifications for a period of at least 6 months after delivery.
Thermal Stability (SADT)
Self-Accelerating Decomposition Temperature (SADT): 60°C (140°F)
The SADT is determined on the basis of the Heat Accumulation Storage Test, which is a recognized test method for organic peroxides according to UN Recommendations on the Transport of Dangerous Goods.
Transport Classification
Classified as:
Organic peroxide type D
Liquid, Division 5.2
UN 3115
Packing Group II
Decomposition Products
Major decomposition products include:
Tert-butanol
Acetone
Methane
2,5-Dimethylhexane-2,5-diol
Frequently Asked Questions
Comprehensive questions and answers about Perodox® 101 applications, safety, and technical specifications
What is 2,5-Dimethyl-2,5-di (tert-butylperoxy) hexane?
What are the primary applications of 2,5-Dimethyl-2,5-di (tert-butylperoxy) hexane?
How does 2,5-Dimethyl-2,5-di (tert-butylperoxy) hexane function as a radical initiator?
What are the key safety considerations when handling 2,5-Dimethyl-2,5-di (tert-butylperoxy) hexane?
What is the recommended storage and shelf life for 2,5-Dimethyl-2,5-di (tert-butylperoxy) hexane?
How is 2,5-Dimethyl-2,5-di (tert-butylperoxy) hexane typically formulated or supplied?
What are the environmental impacts and disposal methods for 2,5-Dimethyl-2,5-di (tert-butylperoxy) hexane?
How does 2,5-Dimethyl-2,5-di (tert-butylperoxy) hexane compare to other peroxides like benzoyl peroxide or dicumyl peroxide?
What are the optimal temperature and conditions for using 2,5-Dimethyl-2,5-di (tert-butylperoxy) hexane in polymer processing?
How can 2,5-Dimethyl-2,5-di (tert-butylperoxy) hexane enhance SEO and LLM visibility for Perodox-101 content?
What is the CAS Number for 2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane?
What is the molecular formula and weight of 2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane?
What is the active oxygen content of Perodox® 101?
What does ADH look like and what is its physical state?
What is the density of 2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane?
What is the melting and boiling point of ADH?
What is the refractive index of this peroxide?
What are the primary applications of 2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane?
Why is ADH considered a "high-temperature" initiator?
What is the 1-hour half-life temperature for ADH?
What is the SADT (Self-Accelerating Decomposition Temperature) for Perodox® 101?
How should ADH be stored safely?
What is the shelf life of Perodox® 101 under proper storage?
What personal protective equipment (PPE) is required when handling ADH?
What are the major decomposition products of ADH?
What is the UN number and transportation classification for ADH?
How does ADH compare to Dicumyl Peroxide (DCP)?
What is a typical dosage for crosslinking polyethylene with ADH?
Can ADH be used for crosslinking silicone rubber?
Is ADH soluble in water?
What is the flash point of ADH?
What is the auto-ignition temperature?
What first aid measures should be taken in case of skin contact?
What first aid measures should be taken in case of eye contact?
What is the vapor pressure of ADH?
How is ADH typically packaged?
Can ADH be used in food contact applications?
What is the effect of ADH on the color of the final polymer?
How does the concentration of ADH affect the cure time and properties?
What is a common curing temperature for polyethylene crosslinked with ADH?
What is the compatibility of ADH with common polymer additives?
How should spills of ADH be handled?
What is the recommended disposal method for ADH waste?
What analytical methods are used to test the quality of ADH?
Does ADH require a co-agent for crosslinking?
What industries primarily use ADH?
What is the heat of decomposition for ADH?
What is the thermal conductivity of ADH?
What is the specific heat capacity of ADH?
What is the regulatory status of ADH (REACH, TSCA)?
What is the benefit of ADH's bifunctional structure?
How stable is ADH under normal handling conditions?
Can ADH be used for the polymerization of other monomers besides styrene and ethylene?
What is a key advantage of using peroxide crosslinking (e.g., with ADH) over sulfur curing for polyolefins?
How does particle size or form affect the handling of ADH?
What is the typical gel content achieved in crosslinked polyethylene using ADH?
What are the key advantages of Perodox® 101 from Shandong Do Sender Chemicals?
Where can I get the Safety Data Sheet (SDS) for Perodox® 101?
Who should I contact for technical support regarding the use of ADH in my application?
Organic Peroxides - Perodox®
Hydroperoxides
Ketone Peroxides
Alkyl Peroxides
Acyl Peroxides
Ester Peroxides
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Perodox® HMa
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Manufacture Facility: Fine Chemical Industry Park, Zhangdian District, Zibo City, Shandong Province,China.