Perodox® 121 - tert-Amyl peroxy-2-ethylhexanoate

The chemical formula of tert-Amyl peroxy-2-ethylhexanoate is C₁₃H₂₆O₃.

The molecular weight of tert-Amyl peroxy-2-ethylhexanoate is 230.34 g/mol.

The IUPAC name for CAS 686-31-7 is 2-methylbutan-2-yl 2-ethylhexaneperoxoate.

tert-Amyl peroxy-2-ethylhexanoate is primarily used as a free radical initiator in polymerization processes for vinyl monomers, as a high-temperature curing agent for unsaturated polyesters, and in the production of EVA copolymers.

tert-Amyl peroxy-2-ethylhexanoate appears as a colorless to pale yellow liquid with a characteristic odor.

The density of tert-Amyl peroxy-2-ethylhexanoate is 0.9075 g/cm³ at 20°C.

The boiling point of tert-Amyl peroxy-2-ethylhexanoate is 68°C at 0.5 Torr pressure.

The melting point of tert-Amyl peroxy-2-ethylhexanoate is -62°C.

tert-Amyl peroxy-2-ethylhexanoate is insoluble in water, with a solubility of 17.6 mg/L at 20°C, but it is soluble in common organic solvents.

tert-Amyl peroxy-2-ethylhexanoate must be stored below 10°C (50°F) in a cool, well-ventilated area, away from heat sources and incompatible materials.

The vapor pressure of tert-Amyl peroxy-2-ethylhexanoate is 0.00442 mmHg at 25°C.

The flash point of tert-Amyl peroxy-2-ethylhexanoate is 112.8°C.

The refractive index of tert-Amyl peroxy-2-ethylhexanoate is 1.432 at 20°C.

tert-Amyl peroxy-2-ethylhexanoate may explode if exposed to heat, shock, or friction. It is classified as an organic peroxide (Hazard Class 5.2) and can cause fires.

The UN number for transporting tert-Amyl peroxy-2-ethylhexanoate is UN 3115.

tert-Amyl peroxy-2-ethylhexanoate is classified under Hazard Class 5.2 (Organic Peroxide) for transportation

tert-Amyl peroxy-2-ethylhexanoate falls under Packing Group II for transportation.

The half-life temperatures are: 0.1 hour at 111°C, 1 hour at 91°C, and 10 hours at 73°C.

The optimal curing temperature range for tert-Amyl peroxy-2-ethylhexanoate is 120-160°C.

Recommended PPE includes protective gloves, clothing, goggles, and positive pressure self-contained breathing apparatus.

The GHS classification includes the signal word "Danger" and hazard statement H242: "Heating may cause a fire."

The water solubility of tert-Amyl peroxy-2-ethylhexanoate is 17.6 mg/L at 20°C.

The exact mass of tert-Amyl peroxy-2-ethylhexanoate is 230.188195 g/mol.

The topological polar surface area of tert-Amyl peroxy-2-ethylhexanoate is 35.5 Ų.

Spills should be handled by eliminating ignition sources, using inert damp non-combustible material for containment, and consulting a specialist for cleanup.

The standard packaging is 20 kg polyethylene drums, with temperature-controlled containers for transport.

When stored properly, tert-Amyl peroxy-2-ethylhexanoate has a shelf life of up to three months.

It can initiate polymerization of acrylates, methacrylates, styrene, acrylonitrile, and is used in EVA copolymer production.

For eye contact, immediately flush with running water for at least 20 minutes and seek medical attention.

Use water spray or fog for small fires; flood fire area with water from a distance for large fires. Do not use straight streams.

The heat of vaporization of tert-Amyl peroxy-2-ethylhexanoate is 51.64 kJ/mol.

The surface tension of tert-Amyl peroxy-2-ethylhexanoate is 29.6 dyne/cm.

The molar volume of tert-Amyl peroxy-2-ethylhexanoate is 259.7 cm³.

The molar refractivity of tert-Amyl peroxy-2-ethylhexanoate is 67.46 cm³.

The heavy atom count of tert-Amyl peroxy-2-ethylhexanoate is 16.

The complexity value of tert-Amyl peroxy-2-ethylhexanoate is 199.

The XLogP3 value of tert-Amyl peroxy-2-ethylhexanoate is 3.87.

The hydrogen bond acceptor count for tert-Amyl peroxy-2-ethylhexanoate is 3.

The rotatable bond count for tert-Amyl peroxy-2-ethylhexanoate is 9.

Synonyms include t-Amylperoxy 2-ethylhexanoate, Hexaneperoxoic acid 2-ethyl- 1,1-dimethylpropyl ester, Trigonox 121, and Lupersol 575,Perodox 121

The InChI key for tert-Amyl peroxy-2-ethylhexanoate is IFXDUNDBQDXPQZ-UHFFFAOYSA-N.

The SMILES notation for tert-Amyl peroxy-2-ethylhexanoate is CCOOC(CCCC)C(=O)OOC(C)(C)CC.

The RTECS number for tert-Amyl peroxy-2-ethylhexanoate is SE0540000.

The Beilstein/Gmelin number for tert-Amyl peroxy-2-ethylhexanoate is 1866031.

The EPA Substance Registry System identifies it as Hexaneperoxoic acid, 2-ethyl-, 1,1-dimethylpropyl ester.

tert-Amyl peroxy-2-ethylhexanoate has a characteristic faint, sweet odor.

The vapor density of tert-Amyl peroxy-2-ethylhexanoate is 7.9 (air=1).

The partition coefficient (LogP) of tert-Amyl peroxy-2-ethylhexanoate is 4.56 at 25°C.

Yes, tert-Amyl peroxy-2-ethylhexanoate may explode if exposed to heat, shock, or friction, and the pure form is shock-sensitive and detonable.

Transport requires temperature-controlled containers to maintain the substance at or below the control temperature at all times.

tert-Amyl peroxy-2-ethylhexanoate is soluble in common organic solvents, including saturated hydrocarbons and aromatic hydrocarbons.

The technically pure form is used in industrial applications where high purity is not critical, such as in polymer production.

Prices vary by supplier and quantity

China is a major supplier, with companies like Do Sender Chem

Minimum order quantities vary by supplier, ranging from 1 kilogram to 20 metric tons.

When stored according to manufacturer guidelines, tert-Amyl peroxy-2-ethylhexanoate remains stable for up to three months.

Incompatible materials include strong acids, strong bases, strong reducing agents, and flammable substances.

For inhalation, move victim to fresh air, apply artificial respiration if not breathing, and administer oxygen if breathing is difficult.

For skin contact, remove contaminated clothing and immediately flush skin with running water for at least 20 minutes.

For ingestion, do not induce vomiting and seek immediate medical assistance.

For spills, isolate the area in all directions for at least 50 meters for liquids and consider evacuation for at least 250 meters.

Use water spray or fog for small fires; for large fires, flood the area with water from a distance. Do not use straight streams.

tert-Amyl peroxy-2-ethylhexanoate decomposes violently when rapidly heated to its critical temperature.