Perodox® 25 - tert-Butyl peroxypivalate

tert-Butyl peroxypivalate (TBPV) is an organic peroxide compound with the CAS registry number 927-07-1. It is widely used as a free radical initiator for polymerization reactions, particularly valued for its effectiveness at low temperatures

The molecular formula of tert-Butyl peroxypivalate is C9H18O3

The molecular weight of tert-Butyl peroxypivalate is 174.24 g/mol

tert-Butyl peroxypivalate is a colorless liquid that may solidify below -19°C. Commercial formulations are often pale yellow liquids

The CAS registry number for tert-Butyl peroxypivalate is 927-07-1

Common synonyms include Lupersol 11, Trigonox 25/75, Esperox 31M, Luperox 11, t-Butyl perpivalate, TBPV, and Perbutyl PV

The density of tert-Butyl peroxypivalate is 0.854 g/cm³ at 20°C

The melting point of tert-Butyl peroxypivalate is -17°C

The boiling point of tert-Butyl peroxypivalate is approximately 245.22°C (rough estimate)

No, tert-Butyl peroxypivalate is insoluble in water and ethylene glycol, but it is soluble in most organic solvents

The primary use of tert-Butyl peroxypivalate is as a polymerization initiator for various polymers including polyethylene, polyvinyl chloride (PVC), and acrylic polymers

In PVC production, tert-Butyl peroxypivalate is used as an initiator for the suspension polymerization of vinyl chloride monomers

Yes, tert-Butyl peroxypivalate is commonly used as a polymerization initiator to make acrylic polymers

Emerging applications include use in coatings and adhesives, pharmaceutical intermediates, biopolymers, and as a chemical blowing agent for polymer foams

In the automotive industry, tert-Butyl peroxypivalate is used to produce high-performance polymers for components that require superior thermal stability

In electronics manufacturing, tert-Butyl peroxypivalate is used to produce specialty polymers where precise control over polymerization is critical for electronic applications

Yes, tert-Butyl peroxypivalate finds application in the synthesis of complex molecules and active pharmaceutical ingredients (APIs), particularly in drug delivery systems

tert-Butyl peroxypivalate facilitates the curing process in coatings at lower temperatures, allowing for formulation of high-performance coatings with enhanced thermal stability

The main advantage is its effectiveness as a low-temperature initiator, which allows for energy-efficient polymerization processes and better control over the reaction

Yes, tert-Butyl peroxypivalate plays a role in developing biodegradable polymer materials that align with sustainability goals

tert-Butyl peroxypivalate is flammable and a dangerous fire risk. Heating may cause explosion. It is shock-sensitive and detonable when pure

The UN number for tert-Butyl peroxypivalate is UN 3113

It should be stored in a deep-freeze box at -18°C to -1°C in a well-ventilated area, isolated from other chemicals

Wear protective gloves, safety glasses, protective clothing, and positive pressure self-contained breathing apparatus (SCBA) when handling tert-Butyl peroxypivalate

The flash point of tert-Butyl peroxypivalate is 68-71°C

For small fires, use water spray or fog; if water is not available, use dry chemical, CO₂ or regular foam. For large fires, flood the area with water from a distance

The acute oral toxicity (LD50) for rats is 4300 mg/kg

Move victim to fresh air, call for medical help, administer oxygen if breathing is difficult, remove contaminated clothing, and flush affected areas with water for at least 20 minutes

Absorb spills with vermiculite or other noncombustible material, sweep up, and place in a plastic container for disposal. Burn in a shallow pit in a remote area

The self-accelerating decomposition temperature for the 75% concentrated solution is 29°C

The vapor pressure is 4.02 hPa at 38°C

The refractive index is 1.410 at 20°C

The LogP value is 3.17 at 25°C

tert-Butyl peroxypivalate decomposes at approximately 70°C

It is classified as Organic peroxides, Type C

Commercial formulations are typically available at concentrations up to 75% in mineral spirits, with some suppliers offering purities from 85% to 99.8%

The XLogP3 value is approximately 2.30580

The exact mass is 174.125594432 g/mol

The topological polar surface area is 35.5 Ų

Gas chromatography is commonly used for analysis, with specific conditions including Silicon SE-30 as stationary phase, 80°C column temperature, and naphthalene pentane as internal standard

The global demand for tert-Butyl peroxypivalate is increasing, driven by its versatility as a polymerization initiator and growing applications in sustainable material production

North America, Europe, and the Asia-Pacific region are major consumers, with significant growth in countries like China and India

Stringent regulations like EU's REACH influence market dynamics by requiring comprehensive safety assessments, which can affect supply but also drive innovation in safer formulations

Prices vary based on purity and quantity, with examples ranging from $1.00 per gram for high purity lab quantities to $1000 per metric ton for industrial quantities

It is available in various packaging options including 1kg bags, 25kg bags, 200kg drums, and custom packaging to meet specific requirements

It is shipped in temperature-controlled containers, typically maintained at -18°C to -1°C, with vented caps and outer protective packaging

Key industries include plastics and polymers, automotive, electronics, construction, and pharmaceuticals

Sustainability trends are driving innovation in bio-based feedstocks, energy-efficient manufacturing, and waste reduction in TBPV production

Lead times vary by supplier but average around 7 days for standard orders, with expedited shipping available for urgent requirements

While other organic peroxides exist as alternatives, tert-Butyl peroxypivalate is often preferred for its specific low-temperature initiation properties and efficiency in certain polymerization processes