
Shandong Do Sender Chemicals Co.,Ltd.
- …
Shandong Do Sender Chemicals Co.,Ltd.
- …

Perodox® B - Di-tert-butyl Peroxide
CAS: 110-05-4 | DTBP
High-temperature polymerization initiator for acrylate and methacrylate applications with 10.94% active oxygen content
Product Overview
Within the temperature range of 130-175°C, Perodox B can be used as an initiator for solution polymerization or copolymerization of acrylate and methacrylate, especially in the production of coatings. It can also be used as an initiator for bulk and suspension polymerization or copolymerization.
CAS Number:110-05-4
TSCA Status:Listed on inventory
EINECS/ELINCS No.:203-733-6
Molecular Weight:146.2 g/mol
Active Oxygen Content:10.94%
Appearance:Clear liquid
Density at 20°C:0.800 g/cm³
Viscosity at 20°C:0.9 mPa.s
Applications
Perodox® MEKP is widely used in various industries for resin curing and composite manufacturing
Coatings Production
Solution polymerization initiator for acrylate and methacrylate coatings with excellent film properties
Bulk Polymerization
High-temperature initiator for bulk polymerization processes requiring precise temperature control
Suspension Polymerization
Effective initiator for suspension polymerization of acrylic monomers in aqueous systems
Acrylic Resins Production
Production of high-quality acrylic resins with controlled molecular weights and properties
Technical Data
Comprehensive technical specifications and performance characteristics of Perodox® B
Decomposition Temperature
130-175°C - Ideal for high-temperature polymerization processes
Half-Life Data
0.1 hr at 164°C | 1 hr at 141°C | 10 hr at 121°C
Thermal Stability (SADT)
80°C - Self-Accelerating Decomposition Temperature
Packaging
20KG polyethylene white plastic drums
Half-Life Calculation
The reactivity of an organic peroxide is usually given by its half-life (t½) at various temperatures. For DTBP in chlorobenzene, half-life at other temperatures can be calculated using the following equations:
Formula 1: kd = A·e^(-Ea/RT)
Formula 2: t½ = (ln2)/kd
Where:
Ea = 153.46 kJ/mole
A = 4.20E+15 s⁻¹
R = 8.3142 J/mole·K
T = (273.15 + °C) K
Temperature (°C) Half-Life
164°C 0.1 hour
141°C 1 hour
121°C 10 hours
Safety & Storage
Proper handling and storage procedures for Perodox® B (DTBP)
Storage Conditions
Maximum Temperature: 40°C (104°F)
Minimum Temperature: -30°C (-22°F) to prevent crystallization
When stored according to these recommended conditions, Perodox B will remain within specifications for at least 6 months after delivery.
Transport Classification
DTBP is classified as:
Organic peroxide type E
Liquid, Division 5.2
UN 3107
Decomposition Products
Major decomposition products include:Acetone,Methane,tert-Butanol
Thermal Stability
Organic peroxides are thermally unstable substances which may undergo self-accelerating decomposition. The SADT is determined based on the Heat Accumulation Storage Test according to UN recommendations.
Frequently Asked Questions
Common questions about Perodox® B and its applications
What is Di-tert-butyl peroxide (DTBP) used for?
What is the active oxygen content of Perodox B?
What is the molecular weight of Di-tert-butyl peroxide (DTBP)?
What is the density and viscosity of Perodox B at 20°C?
What is the EINECS/ELINCS number for DTBP?
What temperature range is optimal for DTBP polymerization initiation?
Which polymerization methods is DTBP suitable for?
What types of coatings production benefit from DTBP?
What is the Self-Accelerating Decomposition Temperature (SADT) for Perodox B?
What are the recommended storage temperatures for DTBP?
How long can Perodox B be stored under proper conditions?
How is the half-life of DTBP calculated at different temperatures?
What are the specific half-life values for DTBP at key temperatures?
How is DTBP classified for transportation?
What packaging is used for Perodox B?
What are the major decomposition products of DTBP?
What does the active oxygen content indicate about DTBP's effectiveness?
How does DTBP compare to other organic peroxides in high-temperature applications?
Which industries commonly use Di-tert-butyl peroxide?
What is the TSCA status of DTBP?
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