• Perodox® B - Di-tert-butyl Peroxide

    CAS: 110-05-4 | DTBP

    High-temperature polymerization initiator for acrylate and methacrylate applications with 10.94% active oxygen content

  • Product Overview

    Within the temperature range of 130-175°C, Perodox B can be used as an initiator for solution polymerization or copolymerization of acrylate and methacrylate, especially in the production of coatings. It can also be used as an initiator for bulk and suspension polymerization or copolymerization.

    CAS Number:110-05-4

    TSCA Status:Listed on inventory

    EINECS/ELINCS No.:203-733-6

    Molecular Weight:146.2 g/mol

    Active Oxygen Content:10.94%

    Appearance:Clear liquid

    Density at 20°C:0.800 g/cm³

    Viscosity at 20°C:0.9 mPa.s

  • Applications

    Perodox® MEKP is widely used in various industries for resin curing and composite manufacturing

    Coatings Production

    Solution polymerization initiator for acrylate and methacrylate coatings with excellent film properties

    Bulk Polymerization

    High-temperature initiator for bulk polymerization processes requiring precise temperature control

    Suspension Polymerization

    Effective initiator for suspension polymerization of acrylic monomers in aqueous systems

    Acrylic Resins Production

    Production of high-quality acrylic resins with controlled molecular weights and properties

  • Technical Data

    Comprehensive technical specifications and performance characteristics of Perodox® B

    Decomposition Temperature

    130-175°C - Ideal for high-temperature polymerization processes

    Half-Life Data

    0.1 hr at 164°C | 1 hr at 141°C | 10 hr at 121°C

    Thermal Stability (SADT)

    80°C - Self-Accelerating Decomposition Temperature

    Packaging

    20KG polyethylene white plastic drums

    Half-Life Calculation

    The reactivity of an organic peroxide is usually given by its half-life (t½) at various temperatures. For DTBP in chlorobenzene, half-life at other temperatures can be calculated using the following equations:

    Formula 1: kd = A·e^(-Ea/RT)

    Formula 2: t½ = (ln2)/kd

    Where:

    Ea = 153.46 kJ/mole

    A = 4.20E+15 s⁻¹

    R = 8.3142 J/mole·K

    T = (273.15 + °C) K

    Temperature (°C) Half-Life

    164°C 0.1 hour

    141°C 1 hour

    121°C 10 hours

  • Safety & Storage

    Proper handling and storage procedures for Perodox® B (DTBP)

    Storage Conditions

    Maximum Temperature: 40°C (104°F)

    Minimum Temperature: -30°C (-22°F) to prevent crystallization

    When stored according to these recommended conditions, Perodox B will remain within specifications for at least 6 months after delivery.

    Transport Classification

    DTBP is classified as:

    Organic peroxide type E

    Liquid, Division 5.2

    UN 3107

    Decomposition Products

    Major decomposition products include:Acetone,Methane,tert-Butanol

    Thermal Stability

    Organic peroxides are thermally unstable substances which may undergo self-accelerating decomposition. The SADT is determined based on the Heat Accumulation Storage Test according to UN recommendations.

  • Frequently Asked Questions

    Common questions about Perodox® B and its applications